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Beilstein J. Org. Chem. 2018, 14, 2799–2804, doi:10.3762/bjoc.14.257
Graphical Abstract
Figure 1: Cis–trans isomerization of mono-functionalized S-diazocines 1–5.
Scheme 1: Reaction conditions: i) MeCN, AIBN, NBS; ii) NaBH4, THF; #commercially available iii) BH3·THF compl...
Figure 2: UV spectra of the S-diazocine 4 in cis (black) and in trans (red) configuration after irradiation w...
Figure 3: Left: crystal structure of the iodo-functionalized S-diazocine 3. Right: crystal structure of the u...